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Phase Behavior and ThermodynamicsPVT Properties

Peng-Robinson PVT Equation Formula

P=RTVbaTV(V+b)+b(Vb)P=\frac{RT}{V-b}-\frac{aT}{V(V+b)+b(V-b)}

Peng-Robinson PVT Equation calculates pressure for pvt properties workflows in phase behavior and thermodynamics.

Calculate

How engineers use this formula

Use this formula when the listed inputs (R, T, V, a, b) are known and the assumptions behind the cited pvt properties relationship match the engineering case being checked.

Assumptions

  • Input values are representative for the well, reservoir, fluid, or equipment case being evaluated.
  • The declared units match the field-unit constants used in the formula.
  • The cited formula applies to the selected petroleum engineering workflow.

Limitations

  • The calculation does not replace a full engineering model or operating procedure.
  • Accuracy depends on the source correlation, assumptions, input quality, and unit consistency.

Common mistakes

  • Mixing unit systems without converting the inputs.
  • Using default example values as field recommendations.
  • Applying the formula outside the source assumptions.

Default example

Using the default inputs, P equals 3,159.088542 consistent EOS pressure basis.

Rconsistent EOS units

10.7316

Tabsolute temperature

600

Vconsistent EOS volume basis

2

aconsistent EOS units

1

bconsistent EOS volume basis

0.05

Inputs

R

consistent EOS units

Gas Constant

T

absolute temperature

Absolute Temperature

V

consistent EOS volume basis

EOS Volume Basis

a

consistent EOS units

Peng-Robinson Attraction Parameter

b

consistent EOS volume basis

Peng-Robinson Covolume Parameter

Outputs

P

consistent EOS pressure basis

Pressure

R

consistent EOS units

Gas Constant

a

consistent EOS units

Peng-Robinson Attraction Parameter

Source and review

reviewed

Gas Conditioning and Processing, Campbell, J. M. (1992)

John M. Campbell. 1992. Gas Conditioning and Processing, Campbell Petroleum Series, Vol. 1, Page 48.

source conflict
Source

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