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Phase Behavior and ThermodynamicsGas Properties

Wichert-Aziz Sour Gas Pseudo-Critical Correction Formula

Tpc=TpcϵT'_{pc}=T^*_{pc}-\epsilon

Wichert-Aziz Sour Gas Pseudo-Critical Correction calculates corrected pseudo-critical temperature for gas properties workflows in phase behavior and thermodynamics.

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How engineers use this formula

Use this formula when the listed inputs (T_pc_star, P_pc_star, y_CO2, y_H2S) are known and the assumptions behind the cited gas properties relationship match the engineering case being checked.

Assumptions

  • Input values are representative for the well, reservoir, fluid, or equipment case being evaluated.
  • The declared units match the field-unit constants used in the formula.
  • The cited formula applies to the selected petroleum engineering workflow.

Limitations

  • The calculation does not replace a full engineering model or operating procedure.
  • Accuracy depends on the source correlation, assumptions, input quality, and unit consistency.

Common mistakes

  • Mixing unit systems without converting the inputs.
  • Using default example values as field recommendations.
  • Applying the formula outside the source assumptions.

Default example

Using the default inputs, T_pc_corr equals 349.264557 °R.

T_pc_star°R

370

P_pc_starpsia

670

y_CO2fraction

0.05

y_H2Sfraction

0.10

Inputs

T_pc_star

°R

Uncorrected Pseudo-Critical Temperature

P_pc_star

psia

Uncorrected Pseudo-Critical Pressure

y_CO2

fraction

Carbon Dioxide Mole Fraction

y_H2S

fraction

Hydrogen Sulfide Mole Fraction

Outputs

T_pc_corr

°R

Corrected Pseudo-Critical Temperature

P_pc_corr

psia

Corrected Pseudo-Critical Pressure

Source and review

reviewed

Wichert, E. and Aziz, K. 1971. Compressibility factor of sour natural gases, Canadian Journal of Chemical Engineering 49:267-273.

Source

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