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Phase Behavior and ThermodynamicsFluid Properties

McCain Solution Gas-Water Pressure Derivative Formula

(RswP)T=Fs(B+2CP)\left(\frac{\partial R_{sw}}{\partial P}\right)_T=F_s(B+2CP)

McCain Solution Gas-Water Pressure Derivative calculates brine solution gas-water pressure derivative for fluid properties workflows in phase behavior and thermodynamics.

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How engineers use this formula

Use this formula when the listed inputs (P, T, S) are known and the assumptions behind the cited fluid properties relationship match the engineering case being checked.

Assumptions

  • Input values are representative for the well, reservoir, fluid, or equipment case being evaluated.
  • The declared units match the field-unit constants used in the formula.
  • The cited formula applies to the selected petroleum engineering workflow.

Limitations

  • The calculation does not replace a full engineering model or operating procedure.
  • Accuracy depends on the source correlation, assumptions, input quality, and unit consistency.

Common mistakes

  • Mixing unit systems without converting the inputs.
  • Using default example values as field recommendations.
  • Applying the formula outside the source assumptions.

Default example

Using the default inputs, dRsw_dP equals 0.002927 scf/STB/psi.

Ppsia

3000

Tdeg F

180

Swt%

5

Inputs

P

psia

Pressure

T

deg F

Temperature

S

wt%

Salinity

Outputs

dRsw_dP

scf/STB/psi

Brine Solution Gas-Water Pressure Derivative

dRswp_dP

scf/STB/psi

Pure-Water Solution Gas-Water Pressure Derivative

F_s

dimensionless

Brine Gas-Solubility Salinity Correction Factor

B_mccain_rsw

scf/STB/psi

McCain Pure-Water Rsw Coefficient B

C_mccain_rsw

scf/STB/psi^2

McCain Pure-Water Rsw Coefficient C

Source and review

reviewed

Formation Water PVT Properties, McCain, W.D. Jr., Petroleum Office, AAPG Wiki

McCain, W.D. Jr. 1991. Reservoir-Fluid Property Correlations-State of the Art; Petroleum Office Formation Water PVT Properties.

Source

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